酞菁敏化剂及其在染料敏化太阳电池中的应用(上)
泮廷廷,胡桂祺,孙元伟,乜忠浩,姜国山,杜玉昌,王东亭,张宪玺
摘要(Abstract):
详细介绍了对称型酞菁、轴向酞菁及具有"推-拉"电子结构的不对称酞菁敏化剂的结构和特点,并分别讨论了不同的取代基团对酞菁敏化剂光电转换性能及溶解性的影响。研究发现:具有三维结构的酞菁不仅溶解性能优良,还能在一定程度上提高其光电转换效率;针对溶解性较差的敏化剂,加入一定量的助剂,会对其效率有显著改善。
关键词(KeyWords): 染料敏化太阳电池;敏化剂;酞菁;“推-拉”电子结构;光电转换效率
基金项目(Foundation): 国家重点基础研究发展计划(973)项目(2011CBA00701);; 国家自然科学基金项目(21171084);; 山东省高校优秀科研创新团队项目
作者(Author): 泮廷廷,胡桂祺,孙元伟,乜忠浩,姜国山,杜玉昌,王东亭,张宪玺
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