液态有机物储氢技术发展历程与问题分析DEVELOPMENT HISTORY AND PROBLEM ANALYSIS OF LIQUID ORGANIC HYDROGEN CARRIER TECHNOLOGY
袁胜楠,张龙龙,赵宁,詹惠安,姜韶堃
摘要(Abstract):
储氢技术作为氢能发展的重要环节之一,发展备受瞩目。液态有机物储氢(LOHC)技术因具有化学性质稳定、便于运输、安全性高而成为各国学者研究的热点。从LOHC技术的储氢介质、催化剂和工业应用3个方面,介绍该技术的发展历程,并分析存在的问题。储氢介质的发展经历了从早期的全碳骨架芳香族化合物、氮杂环化合物,到最新研究发现的小分子直链含氮有机物。加、脱氢反应中的催化剂早期以贵金属作为主要催化活性中心,后期则开发了以廉金属或廉-贵双金属作为主要催化活性中心,以降低成本。工业应用方面,LOHC技术则需考虑脱氢反应模式和能源效率问题,以取得更高的经济效益。通过综述LOHC技术的现状及发展中存在的问题,提出改进方向,以期推动该技术进一步发展和工业化应用进程,加速氢能的产业化应用。
关键词(KeyWords): 液态有机物;储氢;催化剂;储氢介质;加氢;脱氢
基金项目(Foundation): 河北省重点研发计划项目(19214603D)
作者(Author): 袁胜楠,张龙龙,赵宁,詹惠安,姜韶堃
DOI: 10.19911/j.1003-0417.tyn20211018.01
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