甲醇重整制氢在燃料电池中的应用
任素贞,刁红敏,宋志玉
摘要(Abstract)：
分别分析了甲醇重整制氢中的蒸气重整、氧化重整和自热重整技术的特点,介绍了近年来甲醇重整制氢在燃料电池中的应用现状及存在的主要问题。
关键词(KeyWords)： 甲醇;重整制氢;燃料电池氢源
基金项目(Foundation):
作者(Author): 任素贞,刁红敏,宋志玉
参考文献(References)：
- [1]Steele B C H,Heinzel A.Materials for fuel-cell technologies[J]. Nature,2001,414:345-352.
- [2]詹姆斯·拉米尼，安德鲁·迪克斯．燃料电池系统—原理·设计·应用(原书第二版)[M]．朱红，译．北京：科学出版社，2006．
- [3]Navarro R M,Pena M A,Fierro J L G.Hydrogen production reactions from carbon feedstocks:fossil fuels and biomass[J].Chemical review,2007,107(10):3952-3991.
- [4]Frank B,Jentoft F C,Soerijanto H,et al.Steam reforming of methanol over copper-containing catalysts:Influence of support mate- rial on microkinetics[J].Journal of Catalysis,2007,246:177-192.
- [5]Jiang C J,Trimm D L,Wainwright M S,et al.Kinetic mechanism for the reaction between methanol and water over a Cu-ZnO-Al_2O_3 catalyst[J].Applied Catalysis A:General,1993,97(2):145-158.
- [6]Shimokawabe M,Arakawa H,Takezawa N.Characterization of copper/zirconia catalysts prepared by an impregnation method[J]. Applied Catalysis,1990,59(1):45-58.
- [7]Busca G,Costantino U,Marmottini F,et al.Methanol steam reforming over ex-hydrotalcite Cu-Zn-Al catalysts[J].Applied Ca- talysis A:General,2006,310:70-78.
- [8]Twigg M V,Spencer M S.Deactivation of copper metal catalysts for methanol decomposition,methanol steam reforming and metha- nol synthesis[J].Topics in Catalysis,2003,22(3-4):191-203.
- [9]Patel S,Pant K K.Influence of preparation method on perfor- mance of Cu(Zn)(Zr)-alumina catalysts for the hydrogen production via steam reforming of methanol[J].Journal of Porous Materials, 2006,13:373-378.
- [10]Taylor C E,Howard B H,Myers C R.Methanol conversion for the production of hydrogen[J].Industrial & Engineering Chemistry Research,2007,in press.
- [11]李瑛，王林山．燃料电池[M]．北京：冶金工业出版社，2000．
- [12]Alejo L,Lago R,Pena M A,et al.Partial oxidation of methanol to produce hydrogen over Cu-Zn-based catalysts[J].Applied Cataly- sis A:General,1997,162(1-2):281-297.
- [13]Espinosa L,Lago R M,Pena M A,et al.Mechanistic aspects of hydrogen production by partial oxidation of methanol over Cu/ZnO catalysts[J].Topics in Catalysis,2003,22:245-251.
- [14]Agrell J,Birgersson H,Boutonnet M,et al.Production of hydrogen from methanol over Cu/ZnO catalysts promoted by ZrO2 and Al2O3[J].Journal of Catalysis,2003,219(2):389-403.
- [15]洪学伦，任素贞．高稳定性甲醇自热重整制氢Zn-Cr催化剂[J]．电源技术，2007，31(3)：194—196．
- [16]Bowers B J,Zhao J L,Ruffo M,et al.Onboard fuel processor for PEM fuel cell vehicles[J].International Journal of Hydrogen Energy, 2007,32(10-11):1437-1442.
- [17]Helmolt von R,Eberle U.Fuel cell vehicles:Status 2007[J]. Journal of Power Sources,2007,165:833-843.
- [18]Schiermeier Q.Hydrogen hopes(special report)[J].Nature, 2007,449:110-111.
- [19]洪学伦．甲醇重整气为燃料的质子交换膜燃料电池[J]．化工学报，2007，58(6)：1564—1567．