殷亮,赵志国,王一丹,徐越,邬俊波

• 1:中国华能集团清洁能源技术研究院有限公司

摘要(Abstract)：

综述了有机光伏器件能量转换效率从低于1%到如今12%关键性里程碑事件,简要概述了柔性大面积有机太阳电池生产技术的发展状况。随着"10%-10"目标(转换效率10%和使用寿命10年)的迫近,有机光伏技术面临着向大面积太阳电池产业化转变的巨大挑战,一些有关有机光伏未来发展方向的意见在本综述中被提出。

关键词(KeyWords)： 有机光伏;本体异质结;转换效率;溶液加工

Abstract:

Keywords:

基金项目(Foundation):

作者(Author): 殷亮,赵志国,王一丹,徐越,邬俊波

参考文献(References)：

• [1]Green M A,Emery K,Warta W.Progress in photovoltaics:research and applications[J].Progress Photovolt,2011,19(5):565-572.
• [2]Service R F.Outlook Brightens for Plastic Solar Cells[J].Science,2011,332:293-293.
• [3]Jack.德国Heliatek公布其有机光伏电池突破12%[EB/OL].http://newenergy.in-en.com/html/newenergy-13571357871701913.html.
• [4]Chamberlain G A.Organic solar cells:A review[J].Solar cells,1983,8(1):47-83.
• [5]Simon J,Andre J J.Molecular semiconductors:photoelectrical properties and solar cells[M].Berl:Springer Verlag,1985.
• [6]Marcel Dekker.Handbook of conducting polymers[M].New York:M.Dekker,1985,689-722.
• [7]Sariciftci N S,Smilowitz L,Wudl F.Photoinduced electron transfer from a conducting polymer to buckminsterfullere ne[J].Science,1992,258:1474-1476.
• [8]Yu G,Hummelen J C,Wudl F.Polymer photovoltaic cells:enhanced efficiencies via a network of internal donor-acceptor heterojunctions[J].Science,1995,270:1789-1791.
• [9]Shaheen S E,Brabec C J,Hummelen J.2.5%efficient organic plastic solar cells[J].Applied Physics Letters,2001,78(6):841-843.
• [10]Camaion G,Ridolfi G,Maggini M.The effect of a mild thermal treatment on the performance of poly(3-alkylthiophene)/fullerene solar cells[J].Advanced Materials,2002,14(23):1735-1738.
• [11]Padinger F,Rittberger R S,Sariciftci N S.Effects of postproduction treatment on plastic solar cells[J].Advanced Functional Materials,2003,13(1):85-88.
• [12]Ma W,Yang C,Heeger A J.Thermally Stable,Efficient polymer solar cells with nanoscale control of the interpenetrating network morphology[J].Advanced Functional Materials,2005,15(10):1617-1622.
• [13]S v e n s s o n M,Z h a n g F,A n d e r s s o n M R,e t a l.H i g hperformance polymer solar cells of an alternating polyfluorene copolymer and a fullerene derivative[J].Advanced Materials,2003,15(12):988-991.
• [14]Chen M H,Hou J H,Yang Y,et al.Effi cient polymer solar cells with thin active layers based on alternating polyfluorene copolymer/fullerene bulk heterojunctions[J].Advanced Material,2009,21(12):4238-4242.
• [15]Song J,Du C,Bo Z S.Silole-containing polymers for higheffi ciency polymer solar cells[J].Journal of Polymer Science Part A:Polymer Chemistry,2011,49(19):4267-4274.
• [16]Zhu Z,Waller D,Brabec C.Panchromatic conjugated polymers containing alternating donor/acceptor units for photovoltaic applications[J].Macromolecules,2007,40(6):1981-1986.
• [17]Peet J,Kim J Y,Coates N E.Effi ciency enhancement in lowbandgap polymer solar cells by processing with alkane dithiols[J].Nature Materials,2007,6:497-500.
• [18]Liang Y Y,Wu Y,Yu L P.Development of new semiconducting polymers for high performance solar cells[J].Journal of American Chemistry Society,2009,131(22):7792-7799.
• [19]Hou J,Yang Y,Chen Y.A polybenzo[1,2-b:4,5-b']dithiophene derivative with deep HOMO Level and its application in high-performance polymer solar cells[J].Angewandte Chemie International Edition,2010,49(8):1500-1503.
• [20]Zhou H,Yang L,You W.Replacing alkoxy groups with alkylthienyl groups:a feasible approach to improve the properties of photovoltaic polymers[J].Angewandte Chemie International Edition,2011,123(41):9871-9876.
• [21]He Z C,Wu H B,Cao Y.Enhanced power-conversion efficiency in polymer solar cells using an inverted device structure[J].Nature Photonics,2012,190:1-5.
• [22]Stephanie T.Heliatek有机串叠型太阳电池转换效率达10.7%[EB/OL].http://www.solarzoom.com/article-11156-1.html.
• [23]Marin V,Terkin E,Schubert U S.Ink-Jet Printing of Electron Donor/Acceptor Blends:Towards Bulk Heterojunction Solar Cells[J].Macromolecular Rapid Communications,2005,26(4):319-324.
• [24]Hoth C N,Brabec C J.High Photovoltaic Performance of Inkjet Printed Polymer:Fullerene Blends[J].Advanced Materials,2007,19(22):3973-3978.
• [25]Ding J M,Ting C,Subramanian V.Patternable polymer bulk heterojunction photovoltaic cells on plastic by rotogravure printing[J].Sol Energy Mater Sol Cells,2009,93(4):459-464.
• [26]Krebs F C.Polymer solar cell modules prepared using roll-toroll methods:Knife-over-edge coating,slot-die coating and screen printing[J].Sol Energy Mater Sol Cells,2009,93(4):465-475.
• [27]Krebs F C.Processing and preparation of polymer and organic solar cells[J].Sol Energy Mater Sol Cells,2009,93(4):393-393.
• [28]Thue T,Larsen-Olsen,Thomas R.Roll-to-roll processed polymer tandem solar cells partially processed from water[J].Solar Energy Materials and Solar Cells,2012,97:43-49.