李恒,石岩,迟铭书,徐秀灵,刘玥,韩舒伦,薛镒贤,付嘉乾

• 1:吉林建筑大学市政与环境工程学院

摘要(Abstract)：

本文对采用水热碳化技术处理废弃生物质的影响因素进行了综述,并分析了以水热碳化技术处理废弃生物质时的反应机理,以及可采用的分子模拟软件;最后针对利用水热碳化技术处理废弃生物质的方式提出了展望和建议。虽然目前利用水热碳化技术处理废弃生物质的方式在能源、农业和工业等领域具有广阔的应用前景,但该技术在无法连续处理原料、处理过程中会消耗一定电能等方面尚存在不足,仍需要进行深入研究,以促进其进一步的应用和发展。

关键词(KeyWords)： 生物质能;废弃生物质;水热碳化;反应机理;分子模拟

Abstract:

Keywords:

基金项目(Foundation): 国家自然科学基金项目(52070088)

作者(Author): 李恒,石岩,迟铭书,徐秀灵,刘玥,韩舒伦,薛镒贤,付嘉乾

DOI: 10.19911/j.1003-0417.tyn20201027.02

参考文献(References)：

• [1]吴倩芳,张付申.水热炭化废弃生物质的研究进展[J].环境污染与防治,2012,34(7):70-75.
• [2]ZHANG X Y,GAO B,ZHAO S N,et al.Optimization of a "coal-like" pelletization technique based on the sustainable biomass fuel of hydrothermal carbonization of wheat straw[J].Journal of cleaner production,2020,242:1-14.
• [3]ZHAO Z,IBRAHIM M M,WANG X D,et al.Properties of biochar derived from spent mushroom substrates[J].BioResources,2019,14(3):5254-5277.
• [4]TASKIN E,BRANA M T,ALTOMARE C,et al.Biochar and hydrochar from waste biomass promote the growth and enzyme activity of soil-resident ligninolytic fungi[J].Heliyon,2019,5(7):1-8.
• [5]CELIKTAS M S,ALPTEKIN F M.Conversion of model biomass to carbon-based material with high conductivity by using carbonization[J].Energy,2019,188:116089.1-116089-11.
• [6]LENG S Q,LI W Y,HAN C,et al.Aqueous phaserecirculation during hydrothermal carbonization of micro algae and soybean straw:A comparison study[J].Bioresour technology,2020,298:1-10.
• [7]SHARMA H B,SARMAH A K,DUBEY B.Hydrothermal carbonization of renewable waste biomass for solid biofuel production:A discussion on process mechanism,the influence of process parameters,environmental performance and fuel properties of hydrochar[J].Renewable and sustainable energy reviews,2020,123:1-22.
• [8]HEIDARI M,DUTTA A,ACHARYA B,et al.A review of the current knowledge and challenges of hydrothermal carbonization for biomass conversion[J].Journal of the energy institute,2019,92(6):1779-1799.
• [9]RODRIGUEZ C C,HEHR T,VOGLHUBER-SLAVINSKY A,et al.Pyrolysis vs.hydrothermal carbonization:Understanding the effect of biomass structural components and inorganic compounds on the char properties[J].Journal of analytical and applied pyrolysis,2019,140:137-147.
• [10]ROMAN S,NABAIS J M V,LAGINHAS C,et al.Hydrothermal carbonization as an effective way of densifying the energy content of biomass[J].Fuel processing technology,2012,103(1):78-83.
• [11]YAN W,HOEKMAN S K,BROCH A,et al.Effect of hydrothermal carbonization reaction parameters on the properties of hydrochar and pellets[J].Environmental progress & sustainable energy,2014,33(3):676-680.
• [12]LI Z Y,YI W M,LI Z H,et al.Preparation of solid fuel hydrochar over hydrothermal carbonization of red jujube branch[J].Energies,2020,13(2):480-489.
• [13]CHEN X F,MA X Q,PENG X W,et al.Conversion of sweet potato waste to solid fuel via hydrothermal carbonization[J].Bioresour technology,2018,249:900-907.
• [14]GAO P,ZHOU Y Y,MENG F,et al.Preparation and characterization of hydrochar from waste eucalyptus bark by hydrothermal carbonization[J].Energy,2016,97:238-245.
• [15]YAO Z L,MA X Q.Hydrothermal carbonization of chinese fan palm[J].Bioresour technology,2019,282:28-36.
• [16]TIPPAYAWONG N,KANTAK ANIT P,KOONAPHAPDEELERT S.Characterization of hydrochar from hydrothermal carbonization of maize residues[J].Energy reports,2020,6:114-118.
• [17]ZHU Y J,SI Y H,WANG X H,et al.Characterization of hydrochar pellets from hydrothermal carbonization of agricultural residues[J].Energy & fuels,2018,32(11):11538-11546.
• [18]WANG T F,ZHAI Y B,ZHU Y,et al.A review of the hydrothermal carbonization of biomass waste for hydrochar formation:Process conditions,fundamentals,and physicochemical properties[J].Renewable and sustainable energy reviews,2018,90:223-247.
• [19]RATHER M A,KHAN N S,GUPTA R.Catalytichydrothermal carbonization of invasive macrophyte hornwort(ceratophyllum demersum)for production of hydro char:A potential biofuel[J].International journal of environmental science and technology,2016,14(6):1243-1252.
• [20]ZHANG Y,JIANG Q,XIE W L,et al.Effects of temperature,time and acidity of hydrothermal carbonization on the hydrochar properties and nitrogen recovery from com stover[J].Biomass and bioenergy,2019,122:175-182.
• [21]HAMID S B A,TEH S J,LIM Y S.Catalytic hydrothermal upgrading of a-cellulose using iron salts as a lewis acid[J].BioResources,2015,10(3):5974-5986.
• [22]HEIDARI M,SALAUDEEN S,DUTTA A,et al.Effects of process water recycling and particle sizes on hydrothermal carbonization of biomass[J].Energy & fuels,2018,32(11):11576-11586.
• [23]WANG F B,WANG J,GU C,et al.Effects of process water recirculation on solid and liquid products from hydrothe rmal carbonization of laminaria[J].Bioresour technology,2019,292:121996.
• [24]FALCO C,BACCILE N,MARIA-MAGDALENA T.Morphological and structural differences between glucose,cellulose and lignocellulosic biomass derived hydrothermal carbons[J].Green chemistry,2011,13(11):3273-3281.
• [25]刘娟.生物质废弃物的水热碳化试验研究[D].杭州:浙江大学.2016.
• [26]WU Q,YU S T,HAO N J,et al.Characterization of pro ducts from hydrothermal carbonization of pine[J].Bioresour technology,2017,244(Part 1):78-83.
• [27]VU T,CHAFFEE A,YAROVSKY I.Investigation of ligninwater interactions by molecular simulation[J].Molecular simulation,2010,28(10):981-991.
• [28]李震,王宏强,高雨航,等.沙柳生物质燃料颗粒致密成型粘结机理研究[J].农业工程学报,2019,35(21):235-241.
• [29]王巍,王云婷,李新宁.热处理对木质纤维素Iβ结构及其力学性能影响的分子动力学模拟[J].生物质化学工程,2019,53(3):33-38.
• [30]GROTE F,ERMILOVA I,LYUBARTSEV A P.Molecular dynamics simulations of furfural and5-hydroxymethylfurfural at ambient and hydrothermal conditions[J].The journal of physical chemistry B,2018,122(35):8416-8428.
• [31]BORRERO-LóPEZ A M,MASSON E,CELZARD A,et al.Modelling the reactions of cellulose,hemicellulose and lignin submitted to hydrothermal treatment[J].Industrial crops and products,2018,124:919-930.
• [32]PECCHI M,BARATIERI M.Coupling anaerobic digestion with gasification,pyrolysis or hydrothermal carbonization:A review[J].Renewable and sustainable energy reviews,2019,105:462-475.